By David B., & John F. Endicott, eds. Rorabacher
content material: Substitution reactions of chelates / Dale W. Margerum --
strain results and substitution mechanisms / T.W. Swaddle --
Proton-transfer response charges and mechanisms / Edward M. Eyring, David B. Marshall, Frank Strohbusch, and R. Süttinger --
Nucleophilic substitution / Mark J. Pellerite and John I. Brauman --
Electron move in weakly interacting structures / Norman Sutin and Bruce S. Brunschwig --
Optical charge-transfer transitions / Thomas J. Meyer --
Observations on atom-transfer reactions / Henry Taube --
a few comparisons among the energetics of electrochemical and homogeneous electron-transfer reactions / Michael J. Weaver and Joseph T. Hupp --
4 elements of the gap dependence of electron-transfer premiums / Ephraim Buhks, Ralph G. Wilkins, Stephan S. Isied, and John F. Endicott --
additional advancements in electron move / R.A. Marcus and Paul Siders --
Mechanistic experiences of electron alternate kinetics utilizing ab initio digital constitution thoughts / Marshall D. Newton --
Inclusion of solvent results in a vibronic coupling version for mixed-valence compounds / K.Y. Wong and P.N. Schatz --
Parameters of electron-transfer kinetics / Noel S. Hush --
impact of prepared assemblies on chemical reactions / J.K. Thomas --
iteration of reactive intermediates through photolysis of transition-metal polyhydride complexes / Gregory L. Geoffroy --
One-electron relief made of tris(2,2'-bipyridine)rhodium(III) / Carol Creutz, Andrew D. Keller, Harold A. Schwarz, Norman Sutin, and Arden P. Zipp --
Proton-transfer reactions in organometallic chemistry / Richard F. Jordan and Jack R. Norton --
Reactivity of coordinated dioxygen / John F. Endicott and Krishan Kumar --
Inorganic response mechanisms : earlier, current and destiny / Ralph G. Wilkins.
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Extra info for Mechanistic Aspects of Inorganic Reactions
There i s good evidence from e a r l i e r s t u d i e s w i t h ammonia, ethylenediamine, and d i e t h y l e n e t r i a m i n e t h a t the reac t i n g amine needs a f o o t h o l d i n an e q u a t o r i a l p o s i t i o n f o r the displacement t o proceed as shown by the mechanisms i n F i g u r e 13. Methyl groups i n the t h i r d r i n g simply make i t s t e r i c a l l y d i f f i c u l t f o r t r i e n t o get a f o o t h o l d and t h i s i s one of the reasons why the r a t e constant i s reduced by as much as f o u r orders of magnitude when two methyl groups are i n the t h i r d ring.
Chem. , 1968, 90, 6963. 43. Youngblood, M. ; Margerum, D. W. Inorg. Chem. 1980, 19, 3072. 44. Bannister, C. ; Margerum, D. , to be published. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. MECHANISTIC ASPECTS O F INORGANIC REACTIONS 30 45. ; Raycheba, J. M. ; Margerum, D. , to be published. 46. ; Billo, E. ; Margerum, D. W. J. Am. Chem. Soc. 1971, 93, 4173. 47. Hamburg, A. ; Margerum, D. , to be published. 1982. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982.
Wang, Y. H. ; Margerum, D. , to be published. 41. Eigen, M. Angew. Chem. Int. Ed. 1964, 3, 1. 42. Pagenkopf, G. ; Margerum, D. W. J. Am. Chem. , 1968, 90, 6963. 43. Youngblood, M. ; Margerum, D. W. Inorg. Chem. 1980, 19, 3072. 44. Bannister, C. ; Margerum, D. , to be published. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. MECHANISTIC ASPECTS O F INORGANIC REACTIONS 30 45. ; Raycheba, J. M. ; Margerum, D. , to be published. 46. ; Billo, E. ; Margerum, D. W. J. Am. Chem.