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Self-Organization of Molecular Systems: From Molecules and by Nino Russo, Victor Ya Antonchenko, Eugene Kryachko

By Nino Russo, Victor Ya Antonchenko, Eugene Kryachko

This booklet unveils and formulates the important positive factors that govern myriads of the molecular self-organization techniques in micro-, nano-, and macro-dimensions from the subsequent key representatives reminiscent of liquid water and aqueous recommendations, and molecular beverages, nanodots, nanoparticles together with gold, solitons, biomolecules comparable to DNA and proteins, biopolymers and biosensors, catalysis, molecular modeling, molecular units, and skinny motion pictures, and to provide one other, extra complex instructions in computational, experimental, and technological components of nano- and bioscience in the direction of engineering novel and robust molecular self-organized assemblies with adapted homes.

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Extra info for Self-Organization of Molecular Systems: From Molecules and Clusters to Nanotubes and Proteins (NATO Science for Peace and Security Series A: Chemistry and Biology)

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Cluster Science 1999, 10, 295–317. 13. Jensen, T. ; Duval, M. ; Kelly, K. ; Schatz, G. ; Duyne, R. P. V. J. Phys. Chem. 1999, 103, 9846–9853. 14. Jensen, T. ; Schatz, G. ; Duyne, R. P. V. J. Phys. Chem B 1999, 103, 2394–2401. 15. Kelly, K. ; Schatz, G. C. J. Phys. Chem. B 2003, 107, 668–677. 16. Kelly, K. ; Jensen, T. ; Lazarides, A. ; Schatz, G. C. ; Marcel-Dekker: New York, 2002, pp. 89–118. 17. Kelly, K. ; Lazarides, A. ; Schatz, G. C. Computing in Science & Engineering 2001, 3, 67–73. 18. Lazarides, A.

1980, 27, 1829–1833. L. Atkinson et al. 46. Umashankar, K. ; Taflove, A. IEEE Trans. Electromagn. Compat. 1982, 24, 397–405. 47. Mur, G. IEEE Trans. Electromagn. Compat. 1981, 23, 377–382. 48. ; Fukai, I. Microwave Opt. Tech. Lett. 1990, 3, 203–205. 49. Joseph, R. ; Hagness, S. ; Taflove, A. Optics Lett. 1991, 16, 1412–1414. 50. Payne, E. ; Shuford, K. ; Schatz, G. ; Mirkin, C. A. J. Phys. Chem. B 2006, 110, 2150–2154. 51. Haynes, C. ; McFarland, A. ; Schatz, G. ; Duyne, R. P. ; K¨all, M. J. Phys.

It was found that the presence of the nitrate anion bound to the Fe atom promotes a sizable distortion of the cavity walls. 5 A away from the Fe atom relative to their position in the oxy trHbN, thus increasing the cavity volume by a factor of ca. 2. Furthermore, the conformational rearrangement of these residues reduces the compactness of the cavity and facilitates the entrance of water molecules to the active site through two non-simultaneous channels (see Fig. 6). The first one is a consequence of the fast relocation of MetE4 side chain that creates a pore in the cavity as the residue moves away from the nitrate anion.

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