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Structural and Electronic Paradigms in Cluster Chemistry by David Michael P. Mingos

By David Michael P. Mingos

Content material: Mathematical cluster chemistry / R.L. Johnston -- Metal-metal interactions in transition steel clusters with n-doner ligands / Z. Lin -- Electron count number as opposed to structural association in clusters in line with a cubic transition steel center with bridging major crew components / J.-F. Halet -- Metallaboranes / T.P. Fehlner -- Clusters with interstitial atoms from the p-block: How do Wade's principles deal with them? / C.E. Housecroft -- various bare clusters of the heavy main-group parts. digital regularities and analogies / J.D. Corbett -- writer index: volumes 1-87

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34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. Roy L. Johnston Wade K (1971) J Chem Soc Chem Commun 792 Wade K (1976) Adv Inorg Chem Radiochem 18:1 Mingos DMP (1972) Nature Phys Sci 236:99 Mingos DMP (1974) J Chem Soc Dalton Trans 133 Mingos DMP, Wales DJ (1990) Introduction to cluster chemistry. Prentice Hall, Englewood Cliffs, NJ Cundy HM, Rollett AP (1981) Mathematical models, 3rd edn. Tarquin, Norfolk Williams R (1979) The geometrical foundation of natural structure (a source book of design).

Tetrahedral Clusters . . . . . . . . . . . . . . . . . . . . 87 © Springer Verlag Berlin Heidelberg 1997 36 Zhenyang Lin and Man-Fai Fan 6 Pentanuclear Metal Clusters . . . . . . . . . . . . . . . . . 56 7 Hexanuclear Metal Clusters . . . . . . . . . . . . . . . . . 2 Octahedral Clusters . . . . . . . . . . . . . . . . . . . . Trigonal Prismatic Clusters . . . . . . . . . . . . . . . . . 57 61 Higher Nuclearity Metal Clusters .

Fowler and Manolopoulos have shown [90] that isolated pentagons only occur in a small percentage of fullerene isomers. Buckminsterfullerene is the smallest fullerene with isolated pentagons and when n_> 70 there is always at least one isomer with isolated pentagons. Given a choice of isomers with the same number of adjacent pentagons, Raghavachari has postulated that the most stable isomers will have the most even distribution of hexagon environments [106]. Mathematical Cluster Chemistry 31 Fig.

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